Lecture 02

Existence

What Kinds of Numbers?

The Hook

Before we count, before we measure, before we compute: what exists?

Three questions. Try to answer each.

Question 1

How many electrons in a helium atom?

Answer: 2

What kind of number is 2? It counts discrete objects. It's a positive integer.

Question 2

What is the bond length of H₂?

Answer: 0.74 Å

What kind of number is 0.74? It measures a continuous quantity. It falls between integers. It's a rational number (74/100).

Question 3

What is the diagonal of a square with side length 1?

Answer: √2 ≈ 1.41421356...

What kind of number is √2? It's not a ratio of integers. The decimal never terminates, never repeats. It's irrational.

Question 4

What are the solutions to x² + 1 = 0?

Answer: ...

There is no real number whose square is -1. Every real number squared is non-negative. Do we stop here? Or do we expand what "number" means?

Recognition

Different questions demand different number systems.

The integers suffice for counting atoms. They fail for measuring lengths.

The rationals suffice for most measurements. They fail for √2.

The reals suffice for geometry. They fail for x² + 1 = 0.

Each limitation drives an expansion. Each expansion reveals structure that was always there.

The Tool: Number Systems

We build from the ground up.

The Natural Numbers

ℕ = {1, 2, 3, 4, 5, ...}

What they're for: Counting discrete objects.

+ ✓
× ✓
- ✗
÷ ✗

The problem: 3 - 5 = ? Subtraction sometimes has no answer in ℕ.

The Integers

ℤ = {..., -3, -2, -1, 0, 1, 2, 3, ...}

What they add: Zero and negative numbers.

Why we need them: Charges (proton +1, electron -1), oxidation states (Fe²⁺, Fe³⁺, Fe⁰).

+ ✓
× ✓
- ✓
÷ ✗

The problem: 3 ÷ 5 = ? Division sometimes has no answer in ℤ.

The Rational Numbers

ℚ = { p/q : p ∈ ℤ, q ∈ ℤ, q ≠ 0 }

What they add: Fractions — ratios of integers.

Why we need them: Measurement (0.74 Å), concentrations (0.1 M), stoichiometry (half a mole).

Representation: Every rational has a decimal that terminates or repeats: 1/4 = 0.25, 1/3 = 0.333..., 1/7 = 0.142857...

+ ✓
× ✓
- ✓
÷ ✓

The problem: The rationals have gaps.

Theorem (Pythagoreans, ~500 BCE): √2 is not rational.

Proof: Suppose √2 = p/q where p, q are integers with no common factor.

Then 2 = p²/q², so p² = 2q².

This means p² is even, so p is even. Write p = 2k.

Then 4k² = 2q², so q² = 2k², so q² is even, so q is even.

But then p and q share factor 2, contradicting our assumption.

Therefore √2 cannot be written as p/q. ∎

The Real Numbers

Irrational numbers fill the gaps: √2, √3, π = 3.14159..., e = 2.71828...

The real numbers ℝ comprise all rationals and irrationals together.

Geometric picture: The real line. Every point corresponds to exactly one real number. No gaps.

The problem: What is √(-1)?

The Real Number Line

0

Zoom in anywhere. Rationals (green) and irrationals (red) are densely packed at every scale.

The Complex Numbers ℂ

The Algebraic Necessity

Consider the equation x² + 1 = 0. This has no solution in ℝ. For any real x, x² ≥ 0, so x² + 1 ≥ 1 > 0.

We have two choices:

  1. Accept that some polynomial equations have no solutions.
  2. Expand our number system.

Mathematicians chose option 2 — and discovered that the expansion reveals deep structure.

Defining the Complex Numbers

We introduce a new number, denoted i, defined by the property:

i² = -1

This is not "imaginary" in the sense of "fake." The term is a historical accident. The number i is exactly as real as -1 or √2. All numbers are abstract entities.

Definition: A complex number is an expression of the form:

z = a + bi

where a, b ∈ ℝ. a is the real part (Re(z) = a), b is the imaginary part (Im(z) = b).

Arithmetic of Complex Numbers

Operation Formula Example
Addition (a+bi) + (c+di) = (a+c) + (b+d)i (3+2i) + (1-5i) = 4-3i
Multiplication (a+bi)(c+di) = (ac-bd) + (ad+bc)i (3+2i)(1-5i) = 13-13i
Conjugate z̄ = a - bi (3+2i)̄ = 3-2i
Modulus |z| = √(a² + b²) |3+4i| = 5

Key property: z · z̄ = a² + b² = |z|². The product of a complex number with its conjugate is always a non-negative real.

The Complex Plane

3
2
z = 3 + 2i
z̄ = 3 - 2i
|z| = 3.606
arg(z) = 33.7°

Powers of i

The powers of i cycle with period 4:

PowerValuePattern
i⁰1n mod 4 = 0
in mod 4 = 1
-1n mod 4 = 2
-in mod 4 = 3
i⁴1Cycle repeats

Powers of i on the Unit Circle

i⁰ = 1

Polar Form and Euler's Formula

Any nonzero complex number can be written:

z = r(cos θ + i sin θ) = re^(iθ)

where r = |z| and θ = arg(z).

This uses Euler's formula:

e^(iθ) = cos θ + i sin θ

The most beautiful equation in mathematics

Setting θ = π gives:

e^(iπ) + 1 = 0

Euler's identity — connecting e, i, π, 1, and 0

Euler's Formula: e^(iθ) Traces the Unit Circle

e^(iθ) = 1 + 0i
cos θ = 1
sin θ = 0

Roots of Unity

The nth roots of 1 are the solutions to zⁿ = 1.

They are e^(2πik/n) for k = 0, 1, 2, ..., n-1. They form a regular n-gon on the unit circle.

The nth Roots of Unity

6 roots

Multiplication: Scaling and Rotating

When you multiply by a complex number z = re^(iθ):

Multiplication Transforms Shapes

1.5
45°

The Fundamental Theorem of Algebra

Theorem: Every polynomial equation of degree n ≥ 1 with complex coefficients has exactly n roots in ℂ (counting multiplicity).

This is why we stop at ℂ:

The complex numbers are the algebraic closure of the reals. There is no need to go further.

Why Chemistry Needs Complex Numbers

Quantum Mechanics

The wavefunction ψ(x, t) is complex-valued:

ψ(x, t) = A e^(i(kx - ωt))

The Schrödinger equation has i built into its structure:

iℏ ∂ψ/∂t = Ĥψ

You cannot do quantum mechanics with real numbers alone.

Oscillations and Waves

Complex exponentials simplify calculations. Compare:

d/dt e^(iωt) = iω e^(iωt)   vs.   d/dt cos(ωt) = -ω sin(ωt)

Spectroscopy

Fourier transforms produce complex results. The magnitude gives amplitude; the phase gives timing.

Molecular Orbitals

Spherical harmonics Y_l^m are complex. The real orbitals p_x, p_y are linear combinations of complex ones.

Complex Wavefunction: ψ = e^(i(kx - ωt))

2
0

The phase oscillates, but |ψ|² = 1 everywhere (uniform probability).

Summary

The Hierarchy

System Symbol Contains Closed under
Natural 1, 2, 3, ... +, ×
Integer ..., -1, 0, 1, ... +, -, ×
Rational p/q (q ≠ 0) +, -, ×, ÷
Real All limits of rationals +, -, ×, ÷, √(≥0)
Complex a + bi All algebra, all √
Operation Formula
Addition (a+bi) + (c+di) = (a+c) + (b+d)i
Multiplication (a+bi)(c+di) = (ac-bd) + (ad+bc)i
Conjugate a+bi → a-bi
Modulus |a+bi| = √(a² + b²)
Polar form z = r(cos θ + i sin θ) = re^(iθ)
Euler e^(iθ) = cos θ + i sin θ

Exercises

Exercise 1: Arithmetic

Compute, expressing answers in the form a + bi:

(a) (2 + 3i) + (4 - i)    (b) (2 + 3i)(4 - i)    (c) (2 + 3i)/(4 - i)    (d) i³    (e) i¹⁰⁰

Exercise 2: Conjugates and Moduli

For z = 3 - 4i:

(a) Find z̄    (b) Find |z|    (c) Verify that z · z̄ = |z|²    (d) Find z + z̄ and z - z̄

Exercise 3: Polar and Exponential Form

(a) Convert z = 1 + i to polar form    (b) Convert z = 2e^(iπ/3) to Cartesian form    (c) What is e^(2πi)?

Exercise 4: Roots

(a) Find both square roots of i    (b) Find all cube roots of 1    (c) Find all fourth roots of -1

Exercise 5: Chemistry Applications

(a) For ψ = e^(ikx), show that |ψ|² = 1 everywhere.

(b) For ψ = A e^(i(kx - ωt)), find ψ* and |ψ|².

(c) In NMR, signals are S(t) = S₀ e^(iωt) e^(-t/T₂). What is |S(t)|²?

Exercise 6: Irrationality

Prove that √3 is irrational. (Follow the structure of the √2 proof.)